[doc] Clarify exception in multiprocessing.cpu_count (GH-23660) (GH-28434)

Previous wording didn't explain the slightly unintuitive behavior.

Co-authored-by: kj <[email protected]>
(cherry picked from commit 24dbe30)

Co-authored-by: Emmanuel Arias <[email protected]>

Author: miss-islington

Doc/library/multiprocessing.rst

@@ -951,7 +951,8 @@ Miscellaneous
    use.  The number of usable CPUs can be obtained with
    ``len(os.sched_getaffinity(0))``
 
-   May raise :exc:`NotImplementedError`.
+   When the number of CPUs cannot be determined a :exc:`NotImplementedError`
+   is raised.
 
    .. seealso::
       :func:`os.cpu_count`